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A [2]catenane displaying pirouetting motion triggered by debenzylation and locked by chloride anion recognition.

Abstract:
Chloride locks the rings: Debenzylation of a chloride-templated N-benzyl pyridinium catenane, allows for a 180° "pirouetting" of the rings in the resulting neutral pyridyl catenane (see scheme). The catenane may be returned to its original co-conformation by chloride recognition as evidenced in solution and in the solid state. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/chem.201101033

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
Chemistry (Weinheim an der Bergstrasse, Germany) More from this journal
Volume:
17
Issue:
28
Pages:
7734-7738
Publication date:
2011-07-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539


Language:
English
Keywords:
Pubs id:
pubs:141487
UUID:
uuid:00f98164-5eaf-4185-bbbd-720650d22026
Local pid:
pubs:141487
Source identifiers:
141487
Deposit date:
2012-12-19
ARK identifier:

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