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Neutral iodotriazole foldamers as tetradentate halogen bonding anion receptors

Abstract:
Neutral tetradentate halogen bond donor foldamers were synthesised and exhibit enhanced anion affinities over their hydrogen bonding analogues, displaying iodide selectivity over lighter halide, carboxylate and dihydrogen phosphate anions. A foldamer with a chiral (S)-binaphthol motif was demonstrated to distinguish between enantiomers of chiral anions.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/c7cc00727b

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Department:
St Cross College
Role:
Author
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Grant:
Doctoral Training in Synthesis for Biology and Medicine (EP/L015838/1)
Agency for Science, Technology and Research, Singapore More from this funder
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Grant:
FP7/2007–2014, ERC Advanced Grant Agreement No. 267426
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
53
Issue:
16
Pages:
2483-2486
Publication date:
2017-02-21
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pubs id:
pubs:679451
URN:
uri:004facf7-ceb9-46c7-a6ce-b51bd75e5003
UUID:
uuid:004facf7-ceb9-46c7-a6ce-b51bd75e5003
Local pid:
pubs:679451
Paper number:
16
Language:
English

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