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Photochromic materials by postpolymerisation surface modification

Abstract:

Photochromic materials are available by a postpolymerization surface modification of diverse polymers in a multistep sequential process mediated, first, by carbene insertion chemistry, second, by diazonium coupling with a tethered precursor, and finally by coupling to a spiropyran. This three-step sequence is efficient, and surface loading densities of 1013 molecules cm-2 are typically achievable, leading to materials with observable photochromic and wettability behavior, which operate over m...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's Version

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Publisher copy:
10.1021/acsomega.8b02521

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Organic Chemistry
Oxford college:
St Peters College
ORCID:
0000-0002-4440-3632
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Funding agency for:
Chng, S
Publisher:
American Chemical Society Publisher's website
Journal:
ACS Omega Journal website
Volume:
3
Issue:
11
Pages:
15554–15565
Publication date:
2018-11-15
Acceptance date:
2018-10-29
DOI:
EISSN:
2470-1343
Pubs id:
pubs:950967
URN:
uri:0012d16b-481a-4db8-8f42-ed1b6af4380c
UUID:
uuid:0012d16b-481a-4db8-8f42-ed1b6af4380c
Local pid:
pubs:950967
Language:
English

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