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UNUSUAL BASE-INDUCED REARRANGEMENT OF EXO-9-OXABICYCLO[4.2.1]NON-7-ENE OXIDE TO EXO-8-HYDROXYBICYCLO[3.3.0]OCTAN-2-ONE

Abstract:
Reaction of exo-9-oxabicyclo[4.2.1]non-7-ene oxide with n-BuLi gives exo-8-hydroxybicyclo[3.3.0]octan-2-one. Potential reaction pathways for this unusual rearrangement were evaluated with the aid of computational studies. The process is proposed t...Expand abstract...
Publication status:
Published

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Publisher copy:
10.3987/COM-11-S(P)35

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Stent, MAH More by this author
Wilson, FX More by this author
Journal:
HETEROCYCLES More in this journal
Volume:
84
Issue:
1
Pages:
625-635
Publication date:
2012-01-19
DOI:
EISSN:
1881-0942
ISSN:
0385-5414
URN:
uuid:dcca5eaf-c6f1-4ec5-963f-f974d8e6ed6a
Source identifiers:
313394
Local pid:
pubs:313394
Language:
English
Keywords:

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