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Diels-Alder reactivities of strained and unstrained cycloalkenes with normal and inverse-electron-demand dienes: activation barriers and distortion/interaction analysis.

Abstract:
The Diels-Alder reactions of the cycloalkenes, cyclohexene through cyclopropene, with a series of dienes--1,3-dimethoxybutadiene, cyclopentadiene, 3,6-dimethyltetrazine, and 3,6-bis(trifluoromethyl)tetrazine--were studied with quantum mechanical c...Expand abstract...
Publication status:
Published

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Publisher copy:
10.1021/ja408437u

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Journal:
Journal of the American Chemical Society More in this journal
Volume:
135
Issue:
41
Pages:
15642-15649
Publication date:
2013-10-19
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:a1db68f7-e9a4-406a-8932-0847775cd651
Source identifiers:
429308
Local pid:
pubs:429308
Language:
English

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