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Asymmetric total synthesis of (+)-bermudenynol, a C15 Laurencia metabolite with a vinyl chloride containing oxocene skeleton, through intramolecular amide enolate alkylation.

Abstract:
A substrate-controlled asymmetric total synthesis of (+)-bermudenynol, a compact and synthetically challenging C15 Laurencia metabolite that contains several halogen atoms, is reported. The oxocene core, which contains a vinyl chloride, was constr...Expand abstract...
Publication status:
Published

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Publisher copy:
10.1002/anie.201308077

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Journal:
Angewandte Chemie (International ed. in English) More in this journal
Volume:
53
Issue:
1
Pages:
272-276
Publication date:
2014-01-19
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:9c36ad13-5d32-4db6-b706-49ea257a796d
Source identifiers:
438899
Local pid:
pubs:438899
Language:
English
Keywords:

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