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Experimental Diels-Alder reactivities of cycloalkenones and cyclic dienes explained through transition-state distortion energies.

Abstract:
Quantum chemical calculations are used to investigate the experimentally measured reactivities of cyclic dienes and cycloalkenones in the Diels-Alder reaction. The interaction energies (red) are nearly constant; differences arise in changes in dis...Expand abstract...
Publication status:
Published

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Publisher copy:
10.1002/anie.201103998

Authors


Danishefsky, SJ More by this author
Journal:
Angewandte Chemie (International ed. in English) More in this journal
Volume:
50
Issue:
44
Pages:
10366-10368
Publication date:
2011-10-19
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:4c6d57b5-193a-4796-a274-9b6c3d8e087c
Source identifiers:
175216
Local pid:
pubs:175216

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