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Understanding the origins of remote asymmetric induction in the boron aldol reactions of beta-alkoxy methyl ketones.

Abstract:
We report theoretical studies into the remote 1,5-stereoinduction shown by certain types of beta-alkoxy methyl ketones in boron-mediated aldol reactions with achiral aldehydes. For a range of common alkoxy groups, our calculations are in excellent...Expand abstract...
Publication status:
Published

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Publisher copy:
10.1021/ol061671q

Authors


Goodman, JM More by this author
Journal:
Organic letters More in this journal
Volume:
8
Issue:
19
Pages:
4299-4302
Publication date:
2006-09-19
DOI:
EISSN:
1523-7052
ISSN:
1523-7060
URN:
uuid:25c3eb8b-2a19-4c86-8fee-f173fefec211
Source identifiers:
117608
Local pid:
pubs:117608
Language:
English
Keywords:

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