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Mechanistic Study of a Ru-Xantphos Catalyst for Tandem Alcohol Dehydrogenation and Reductive Aryl-Ether Cleavage

Abstract:
We employ density functional theory (DFT) calculations and kinetics measurements to understand the mechanism of a xantphos-containing molecular ruthenium catalyst acting on an alkyl aryl ether linkage similar to that found in lignin to produce ace...Expand abstract...
Publication status:
Published

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Publisher copy:
10.1021/cs400110r

Authors


Chmely, SC More by this author
Ciesielski, PN More by this author
Jimenez-Oses, G More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Journal:
ACS CATALYSIS More in this journal
Volume:
3
Issue:
5
Pages:
963-974
Publication date:
2013-05-19
DOI:
EISSN:
2155-5435
ISSN:
2155-5435
URN:
uuid:075e9618-a9db-4dbb-81f8-84d8e58b9fa8
Source identifiers:
405718
Local pid:
pubs:405718

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