Thesis
New bisphosphine ligands for asymmetric catalysis
- Abstract:
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The success of homogeneous asymmetric catalysis has been attributed to the structure and stereochemistry of the coordinated ligand(s). The most effective ligands are C2-symmetrical bisphosphines containing either a rigid chiral backbone linking two PPh2 units or a bisphosphine, DIPAMP containing two chiral phosphine units linked by an achiral backbone. The synthesis of P-chiral ligands of this type has been severely hindered by the lack of a general synthetic route a...
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- Publication date:
- 1991
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- University of Oxford
- Language:
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English
- Subjects:
- UUID:
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uuid:c1261e8d-baf4-476a-8954-f943588e1579
- Local pid:
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td:603840953
- Source identifiers:
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603840953
- Deposit date:
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2013-10-21
Terms of use
- Copyright holder:
- Carey, Joseph Vincent
- Copyright date:
- 1991
- Notes:
- The digital copy of this thesis has been made available thanks to the generosity of Dr Leonard Polonsky
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