Journal article
The electro-reduction of carbon dioxide in dimethyl sulfoxide at gold microdisk electrodes: Current | voltage waveshape analysis
- Abstract:
- The electro-reduction of carbon dioxide is studied by linear sweep and cyclic voltammetry in DMSO electrolyte solutions and at polycrystalline gold microdisk electrodes. An electrode reaction pathway is suggested. Numerical simulation of the reaction mechanism gives current | potential waveshapes in excellent agreement with those observed experimentally. Kinetic parameters for the reduction process are deduced from this waveshape approach, and the charge-transfer coefficient is found to be approximately 0.43 ± 0.05.
- Publication status:
- Published
Actions
Authors
Bibliographic Details
- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
- Volume:
- 105
- Issue:
- 22
- Pages:
- 5253-5261
- Publication date:
- 2001-06-07
- DOI:
- EISSN:
-
1520-5207
- ISSN:
-
1089-5647
Item Description
- Language:
-
English
- Pubs id:
-
pubs:37853
- UUID:
-
uuid:878456a8-f27c-4122-80e3-566cd3595736
- Local pid:
-
pubs:37853
- Source identifiers:
-
37853
- Deposit date:
-
2012-12-19
Terms of use
- Copyright date:
- 2001
Metrics
If you are the owner of this record, you can report an update to it here: Report update to this record